Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction-Reference-Cited by-同舟云学术

Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction

Published:2018 Issue:31 Volume:9 Page:6580-6588
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hartmann Nathaniel J.¹²³⁴,Wu Guang¹²³⁴,Hayton Trevor W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Santa Barbara

4. 93106 USA

Abstract

The “masked” terminal nickel sulfide [K(18-crown-6)][L^tBuNi^II(S)] mediates the reduction of N₂O by CO, via the thioperoxide complex [K(18-crown-6)][L^tBuNi^II(η²-SO)].

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02536C

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