Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of California
3. Santa Barbara
4. 93106 USA
Abstract
The “masked” terminal nickel sulfide [K(18-crown-6)][LtBuNiII(S)] mediates the reduction of N2O by CO, via the thioperoxide complex [K(18-crown-6)][LtBuNiII(η2-SO)].
Funder
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02536C
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