Mechanistic insights into asymmetric transfer hydrogenation of pyruvic acid catalysed by chiral osmium complexes with formic acid assisted proton transfer-Reference-Cited by-同舟云学术

Mechanistic insights into asymmetric transfer hydrogenation of pyruvic acid catalysed by chiral osmium complexes with formic acid assisted proton transfer

Published:2019 Issue:65 Volume:55 Page:9633-9636
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Wan¹²³⁴⁵^ORCID,Yang Xinzheng¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. State Key Laboratory for Structural Chemistry of Unstable and Stable Species

3. CAS Research/Education Center for Excellence in Molecular Sciences

4. Institute of Chemistry Chinese Academy of Sciences

5. Beijing 100190

Abstract

Density functional theory calculations reveal a proton-coupled hydride transfer mechanism with the participation of formic acid for asymmetric transfer hydrogenation of pyruvic acid catalyzed by chiral Os complexes.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04760C

Reference35 articles.

2. Aqueous-phase asymmetric transfer hydrogenation of ketones ? a greener approach to chiral alcohols

3. Asymmetric homogeneous hydrogenations at scale

4. Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions

5. Asymmetric transfer hydrogenation: chiral ligands and applications

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Intramolecular Proton-Coupled Hydride Transfers with Relatively Low Activation Barriers;The Journal of Physical Chemistry A;2023-06-27

2. Base-Free Transfer Hydrogenation Catalyzed by Ruthenium Hydride Complexes of Coumarin-Amide Ligands;ACS Sustainable Chemistry & Engineering;2023-05-26

3. Density functional theory investigation of Ru(ii) and Os(ii) asymmetric transfer hydrogenation catalysts;Faraday Discussions;2022

4. Osmium-catalyzed reduction processes;Russian Chemical Reviews;2022

5. Arene-Osmium(II) Complexes in Homogeneous Catalysis;Inorganics;2021-07-12