Density functional theory investigation of Ru(<scp>ii</scp>) and Os(<scp>ii</scp>) asymmetric transfer hydrogenation catalysts-Reference-Cited by-同舟云学术

Density functional theory investigation of Ru(ii) and Os(ii) asymmetric transfer hydrogenation catalysts

Published:2022 Issue: Volume:234 Page:264-283
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Bolitho Elizabeth M.¹^ORCID,Coverdale James P. C.²^ORCID,Wolny Juliusz A.³^ORCID,Schünemann Volker³^ORCID,Sadler Peter J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK

2. School of Pharmacy, Institute of Clinical Sciences, University of Birmingham, Edgbaston, B15 2TT, UK

3. Fachbereich Physik, Technische Universität Kaiserslautern, Kaiserslautern, Germany

Abstract

Density functional theory calculations reveal subtle differences between the mechanism of asymmetric transfer hydrogenation of a ketone by half-sandwich Ru(ii) and Os(ii) arene catalysts with 5 chiral centres with formate as the hydride source.

Funder

Diamond Light Source

University of Warwick

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D1FD00075F

Reference43 articles.

1. Thermodynamic and kinetic hydricities of metal-free hydrides

2. Transfer hydrogenation catalysis in cells

3. Asymmetric hydrogenation of ketones: Tactics to achieve high reactivity, enantioselectivity, and wide scope

4. Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes

5. Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A novel approach for the synthesis of (S)-tolvaptan and (S)-desmethyltolvaptan;Tetrahedron Letters;2024-09

2. Targeting cancer lactate metabolism with synergistic combinations of synthetic catalysts and monocarboxylate transporter inhibitors;JBIC Journal of Biological Inorganic Chemistry;2023-03-08

3. Os(ii) complexes for catalytic anticancer therapy: recent update;Chemical Communications;2022