Double layer capacitances analysed with impedance spectroscopy and cyclic voltammetry: validity and limits of the constant phase element parameterization-Reference-Cited by-同舟云学术

Double layer capacitances analysed with impedance spectroscopy and cyclic voltammetry: validity and limits of the constant phase element parameterization

Published:2021 Issue:37 Volume:23 Page:21097-21105
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schalenbach Maximilian¹^ORCID,Durmus Yassin Emre¹^ORCID,Tempel Hermann¹^ORCID,Kungl Hans¹,Eichel Rüdiger-A.¹

Affiliation:

1. Fundamental Electrochemistry (IEK-9), Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany

Abstract

At small amplitudes, the equilibrium positions of the ions are changed. High amplitudes lead to a drastic distortion of the ion arrangement in the double layer, increasing the capacitance and asymmetric ion movements.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03381F

Reference33 articles.

1. New models for the structure of the electrochemical interface

2. Modelling the electric double layer at electrode/electrolyte interfaces

3. Combining theory and experiment in advancing fundamental electrocatalysis