Competing amination and C–H arylation pathways in Pd/xantphos-catalyzed transformations of binaphthyl triflates: switchable routes to chiral amines and helicene derivatives-Reference-Cited by-同舟云学术

Competing amination and C–H arylation pathways in Pd/xantphos-catalyzed transformations of binaphthyl triflates: switchable routes to chiral amines and helicene derivatives

Published:2016 Issue:34 Volume:14 Page:8123-8140
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ruch Aaron A.¹²³⁴,Handa Sachin¹⁵⁶⁴,Kong Fanji¹²³⁴,Nesterov Vladimir N.¹²³⁴,Pahls Dale R.¹²³⁴,Cundari Thomas R.¹²³⁴,Slaughter LeGrande M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of North Texas

3. Denton

4. USA

5. Oklahoma State University Stillwater

6. Oklahoma

Abstract

A Pd(OAc)₂/xantphos catalyst system can be tuned to promote either amination or C–H arylation of hindered binaphthyl 2-triflates, with xantphos's hemilability playing a key role.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01102K

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