Intramolecular rearrangements guided by adaptive coordination-driven reactions toward highly luminescent polynuclear Cu(i) assemblies

Author:

El Sayed Moussa Mehdi12345,Khalil Ali Moustafa12345,Evariste Sloane12345ORCID,Wong Hok-Lai678910,Delmas Vincent12345,Le Guennic Boris12345ORCID,Calvez Guillaume12345ORCID,Costuas Karine12345ORCID,Yam Vivian Wing-Wah678910ORCID,Lescop Christophe12345ORCID

Affiliation:

1. Univ Rennes

2. INSA Rennes

3. CNRS

4. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226

5. F-35000 Rennes

6. Institute of Molecular Functional Materials Areas of Excellence Scheme

7. University Grants Committee (Hong Kong) and Department of Chemistry

8. The University of Hong Kong

9. Hong Kong

10. P.R. China

Abstract

Highly luminescent solid-state Cu6, Au2Cu10 and Pt4Cu11 derivatives are obtained in one step reaction thanks to adaptive coordination-driven supramolecular chemistry using pre-assembled flexible Cu(i) precursors.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Alexander von Humboldt-Stiftung

Grand Équipement National De Calcul Intensif

University of Hong Kong

University Research Committee, University of Hong Kong

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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