Phase dependence and mechanical and thermal ductility of the luminescence properties of tetranuclear Cu(<scp>i</scp>) metallacycle assemblies stabilized by ditopic organo-pnictogen (P,As) ligands-Reference-Cited by-同舟云学术

Phase dependence and mechanical and thermal ductility of the luminescence properties of tetranuclear Cu(i) metallacycle assemblies stabilized by ditopic organo-pnictogen (P,As) ligands

Published:2023 Issue:23 Volume:10 Page:6976-6989
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Lecourt Constance¹,Utrera Melero Raquel¹,Schiller Jana¹²,Moutier Florent¹,Dorcet Vincent¹,Calvez Guillaume¹^ORCID,Poidevin Corentin¹,Costuas Karine¹^ORCID,Scheer Manfred²^ORCID,Lescop Christophe¹^ORCID

Affiliation:

1. Univ. Rennes, INSA Rennes, CNRS, ISCR – UMR6226, F-35000 Rennes, France

2. Department of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany

Abstract

A tetranuclear Cu(i) metallacycle stabilized by ditopic organo-pnictogen (P,As) ligands presents stimuli-sensitive luminescence whose origin is compared with those based on congener (P,P) ligands, revealing competitive effects involving solid-state packing and spin–orbit coupling.

Funder

Centre National de la Recherche Scientifique

Agence Nationale de la Recherche

Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation

Ministère des Affaires Etrangères

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Grand Équipement National De Calcul Intensif

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry