Intramolecular rotations and electronic states of iron in the iron bis(dicarbollide) complex Fe[(C2B9H11)2] studied by a 57Fe nuclear probe and computational methods-Reference-Cited by-同舟云学术

Intramolecular rotations and electronic states of iron in the iron bis(dicarbollide) complex Fe[(C2B9H11)2] studied by a 57Fe nuclear probe and computational methods

Published:2022 Issue:3 Volume:58 Page:391-394
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bednarska-Szczepaniak Katarzyna¹,Dziedzic-Kocurek Katarzyna²,Przelazły Ewelina¹,Stanek Jan²^ORCID,Leśnikowski Zbigniew J.¹^ORCID

Affiliation:

1. Laboratory of Medicinal Chemistry, Institute of Medical Biology PAS, Lodowa 106, Łódź 92-232, Poland

2. Marian Smoluchowski Institute of Physics, Jagiellonian University, Prof. Stanisława Łojasiewicza 11, Kraków 30-345, Poland

Abstract

The rotation of iron bis(dicarbollide) complexes was characterized by Mössbauer spectroscopy and computational methods. Unexpected FeII-like character in the 8-dioxane iron bis(dicarbollide) adduct was discovered.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05111C

Reference16 articles.

1. Metallacarboranes in the new millennium

2. Metallacarboranes and their interactions: theoretical insights and their applicability

3. Electrical or Photocontrol of the Rotary Motion of a Metallacarborane

4. P.Gutlich , E.Bill and A. X.Trautwein , Mössbauer Spectroscopy and Transition Metal Cemistry , Spinger-Verlag , Berlin Heidelberg , 2011 , p. 15

5. 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules

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