Molecular design of cage iron(ii) and cobalt(ii,iii) complexes with a second fluorine-enriched superhydrophobic shell-Reference-Cited by-同舟云学术

Molecular design of cage iron(ii) and cobalt(ii,iii) complexes with a second fluorine-enriched superhydrophobic shell

Published:2015 Issue:8 Volume:44 Page:3773-3784
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Belov Alexander S.¹²³,Zelinskii Genrikh E.¹²³,Varzatskii Oleg A.⁴⁵⁶,Belaya Irina G.¹²³,Vologzhanina Anna V.¹²³,Dolganov Alexander V.¹²³,Novikov Valentin V.¹²³,Voloshin Yan Z.¹²³

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2. 119991 Moscow

3. Russia

4. Vernadskii Institute of General and Inorganic Chemistry of the National Academy of Sciences of Ukraine

5. 03680 Kyiv

6. Ukraine

Abstract

Pentafluorophenylboron-capped iron and cobalt(ii) hexachloroclathrochelate precursors undergo nucleophilic substitution giving the fluorine-enriched cage complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03628J

Reference22 articles.

1. Cage iron(II) complexes with apical and ribbed adamantyl substituents: The creation of second (hydrophobic) shell of an encapsulated metal ion

2. Ribbed-functionalized iron(ii) tris-dioximate clathrochelates with pendant fragments of various types: synthetic pathways, structures, and properties

3. First example of perfluoroalkylation of a quasi-aromatic encapsulating ligand: 2,5-Dithiahexane-assisted reaction of the iron(II) diiodoclathrochelate with trifluoromethylcopper(I)

4. Formation of the second superhydrophobic shell around an encapsulated metal ion: synthesis, X-ray structure and electrochemical study of the clathrochelate and bis-clathrochelate iron(ii) and cobalt(ii,iii) dioximates with ribbed perfluoroarylsulfide substituents

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