Coordination-induced metal-to-macrocycle charge transfer and effect of cations on reorientation of the CN ligand in the {SnL2Mac}2− dianions (L = CN−, OCN−, Im−; Mac = phthalo- or naphthalocyanine)-Reference-Cited by-同舟云学术

Coordination-induced metal-to-macrocycle charge transfer and effect of cations on reorientation of the CN ligand in the {SnL2Mac}2− dianions (L = CN−, OCN−, Im−; Mac = phthalo- or naphthalocyanine)

Published:2019 Issue:15 Volume:48 Page:4961-4972
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Konarev Dmitri V.¹²³^ORCID,Kuzmin Alexey V.⁴²³,Shestakov Alexander F.¹²³⁵⁶,Khasanov Salavat S.⁴²³,Lyubovskaya Rimma N.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. 142432 Russia

4. Institute of Solid State Physics RAS

5. Lomonosov Moscow State University

6. Leninskie Gory

Abstract

Anionic coordination {crypt(M⁺)}₂{SnL₂Mac}²⁻ complexes of tin(ii) phthalo- (Pc) and naphthalocyanines (Nc) were obtained and discussed.

Funder

Russian Science Foundation

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00655A

Reference52 articles.

1. Phthalocyanines and Phthalocyanine Analogues: The Quest for Applicable Optical Properties

2. Practical Applications of Phthalocyanines – from Dyes and Pigments to Materials for Optical, Electronic and Photo-electronic Devices

3. A new class of highly conductive molecular solids: the partially oxidized phthalocyanines

4. A highly conducting partially oxidized salt of axially substituted phthalocyanine. Structure and physical properties of TPP[Co(Pc)(CN)2]2 {TPP=tetraphenylphosphonium, [Co(Pc)(CN)2]=dicyano(phthalocyaninato)cobalt(III)}

5. Variable magnetotransport properties in the TPP[Fe(Pc)L2]2system (TPP = tetraphenylphosphonium, Pc = phthalocyaninato, L = CN, Cl, and Br)

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