Macrocycle- and metal-centered reduction of metal tetraphenylporphyrins where the metal is copper(ii), nickel(ii) and iron(ii)-Reference-Cited by-同舟云学术

Macrocycle- and metal-centered reduction of metal tetraphenylporphyrins where the metal is copper(ii), nickel(ii) and iron(ii)

Published:2021 Issue:43 Volume:50 Page:15620-15632
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nazarov Dmitry I.¹,Andronov Mikhail G.¹²,Kuzmin Aleksey V.³,Khasanov Salavat S.³,Yudanova Evgeniya I.¹,Shestakov Alexander F.¹²,Otsuka Akihiro⁴⁵^ORCID,Yamochi Hideki⁴⁵^ORCID,Kitagawa Hiroshi⁴^ORCID,Konarev Dmitri V.¹^ORCID

Affiliation:

1. Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow region, 142432 Russia

2. Moscow State University, Leninskie Gory, 119991 Moscow, Russia

3. Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432 Russia

4. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

5. Research Center for Low Temperature and Materials Sciences, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

Crystalline salts of metal tetraphenylporphyrins (M = Ni, Cu and Fe) are obtained in crystalline state and studied. Possibility of the doublet-quartet transition from {NiI(TPP2−)}− to {NiII(TPP·3−)}−is shown.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Japan Society for the Promotion of Science

Japan Science and Technology Corporation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02573B

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5. A new class of highly conductive molecular solids: the partially oxidized phthalocyanines

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