Iron phthalocyanine derived Fe1/h-BN single atom catalysts for CO2 hydrogenation

Author:

Leybo Denis V.1ORCID,Ryzhova Anastasia A.1ORCID,Matveev Andrei T.1,Firestein Konstantin L.2ORCID,Tarakanov Pavel A.3ORCID,Konopatsky Anton S.1ORCID,Trigub Alexander L.4,Sukhanova Ekaterina V.5ORCID,Popov Zakhar I.56ORCID,Golberg Dmitri V.27ORCID,Shtansky Dmitry V.1ORCID

Affiliation:

1. National University of Science and Technology “MISiS”, Leninsky Prospect 4, 119049 Moscow, Russia

2. Centre for Materials Science, School of Chemistry and Physics, Faculty of Science, Queensland University of Technology, Brisbane, QLD 4000, Australia

3. Institute of Physiologically Active Compounds at Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 1 Severny Proezd, 142432 Chernogolovka, Russia

4. National Research Center Kurchatov Institute, 123182, Moscow, Russia

5. Emanuel Institute of Biochemical Physics RAS, 199334, Moscow, Russia

6. Plekhanov Russian University of Economics, 36 Stremyanny per., 117997, Moscow, Russia

7. Research Centre for Materials Nanoarchitectonics, National Institute for Materials Science (NIMS), Namiki 1, Tsukuba, Ibaraki 305, Japan

Abstract

Fe1/h-BN single atom catalysts can be successfully synthesized using heat treatment of Fe phthalocyanine decorated h-BN in an oxygen atmosphere. Selectivity toward hydrocarbons can be controlled by the presence of Fe nanoparticles.

Funder

Australian Research Council

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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