Switchable tuning selectivity of CO2 hydrogenation via anion-modification of the Ru/TiO2 catalyst

Author:

Zhang Jin12,Huang Tianfen13,Wang Ruiyi1ORCID,Li Xincheng14,Wang Jing14,Ge Hui1,Ren Jun2ORCID,Wang Yunwei1,Zheng Zhanfeng14ORCID

Affiliation:

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

2. Shanxi Institute of Science and Technology, Jincheng 048000, China

3. School of Chemical Engineering and Technology, North University of China, Taiyuan 030051, China

4. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Various anions introduced onto the surface of the Ru/TiO2 catalyst have strong interactions with Ru active sites, affecting the adsorption of CO, thus realizing the transformation of product selectivity from CH4 to CO in the hydrogenation of CO2.

Funder

National Natural Science Foundation of China

ShanXi Science and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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