Low-spin [MII(L)2] and [MIII(L)2]+ (M = Fe and Co) complexes of tridentate azo-containing pyridine/pyrazine amide ligands: structures, properties and redox potential correlations-Reference-Cited by-同舟云学术

Low-spin [MII(L)2] and [MIII(L)2]+ (M = Fe and Co) complexes of tridentate azo-containing pyridine/pyrazine amide ligands: structures, properties and redox potential correlations

Published:2017 Issue:34 Volume:46 Page:11291-11305
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sengupta Arunava¹²³⁴,Rajput Amit¹²³⁴,Barman Suman K.¹²³⁴,Mukherjee Rabindranath¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur 208 016

4. India

Abstract

Comparative molecular (X-ray) and electronic (DFT, TD-DFT) structural studies have been done; the E_1/2 values (M^III/M^II couple) for Fe, Co and Ni complexes linearly correlate with other low-spin complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01577A

Reference103 articles.

1. Coordination chemistry with pyridine/pyrazine amide ligands. Some noteworthy results

2. Bispyridylamides?coordination chemistry and applications in catalytic reactions

3. Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry

4. Designing Ligands for Oxidizing Complexes

5. Syntheses, electrochemistry and reactivities of pyridine amide complexes of chromium(III) and manganese(III)

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