CO2-Activation by size-selected tantalum cluster cations (Ta1–16+): thermalization governing reaction selectivity-Reference-Cited by-同舟云学术

CO₂-Activation by size-selected tantalum cluster cations (Ta_1–16⁺): thermalization governing reaction selectivity

Published:2022 Issue:4 Volume:24 Page:2623-2629
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Levin Nikita¹,Margraf Johannes T.²³^ORCID,Lengyel Jozef¹^ORCID,Reuter Karsten²³^ORCID,Tschurl Martin¹^ORCID,Heiz Ulrich¹^ORCID

Affiliation:

1. Lehrstuhl für Physikalische Chemie, Chemistry Department & Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, Garching 85748, Germany

2. Lehrstuhl für Theoretische Chemie, Chemistry Department & Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, Garching 85748, Germany

3. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, Berlin D-14195, Germany

Abstract

Tantalum cluster cations react with CO2 either via transfer of oxygen atoms to the clusters or the adsorption of an entire molecule. The released energy and vibrational heat capacities are assigned to determine the branching ratios of the pathways.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04469A

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