Ta+ and Nb+ + CO2: intersystem crossing in ion–molecule reactions-Reference-Cited by-同舟云学术

Ta⁺ and Nb⁺ + CO₂: intersystem crossing in ion–molecule reactions

Published:2024 Issue:11 Volume:26 Page:8670-8680
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Huber Maximilian E.¹^ORCID,Lewis Tucker W. R.²,Meta Marcel¹^ORCID,Ard Shaun G.²,Liu Yang³,Sweeny Brendan C.²,Guo Hua³^ORCID,Ončák Milan⁴^ORCID,Shuman Nicholas S.²,Meyer Jennifer¹^ORCID

Affiliation:

1. RPTU Kaiserslautern-Landau, Fachbereich Chemie und Forschungszentrum OPTIMAS, Erwin-Schrödinger Str. 52, 67663 Kaiserslautern, Germany

2. Air Force Research Laboratory, Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117, USA

3. Department of Chemistry and Chemical Biology, Center for Computational Chemistry, University of New Mexico, Albuquerque, New Mexico 87131, USA

4. Universität Innsbruck, Institut für Ionenenphysik und Angewandte Physik, Technikerstra. 25, 6020 Innsbruck, Austria

Abstract

The role of intersystem crossing (ISC) in the dynamics and kinetics of gas-phase ion–molecule reactions is investigated by a mix of experimental and theoretical methods. We found that ISC can act as a bottleneck even for highly efficient reactions.

Funder

European Office of Aerospace Research and Development

Deutsche Forschungsgemeinschaft

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP05549C

Reference56 articles.

1. Two‐State Reactivity: Personal Recounting of its Conception and Future Prospects

2. Two-State Reactivity as a New Concept in Organometallic Chemistry

3. FeO⊕ Activates Methane

4. The Dynamics of the Reaction of FeO+ and H2 : A Model for Inorganic Oxidation

5. Understanding the reactivity bottleneck in the spin-forbidden reaction FeO++H2→Fe++H2O

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