Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(<scp>vi</scp>) nitrido complexes-Reference-Cited by-同舟云学术

Facile C–N bond cleavage of primary aliphatic amines by (salen)ruthenium(vi) nitrido complexes

Published:2022 Issue:14 Volume:51 Page:5404-5408
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pan Yunling¹,Cheng Lin²,Pan Yi²^ORCID,Man Wai-Lun³^ORCID,Yiu Shek-Man²,Xie Jianhui¹^ORCID,Lau Kai-Chung²^ORCID,Lau Tai-Chu²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, People's Republic of China

2. Department of Chemistry, City University of Hong Kong, Kowloon Tong, Hong Kong, P R China

3. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong 999077, People's Republic of China

Abstract

A (salen)ruthenium(vi) nitrido complex reacts rapidly with primary amines leading to C–N bond cleavage owing to the formation of stable NN after the initial coupling of the amine N and the nitrido ligand.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

City University of Hong Kong

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00600F

Reference31 articles.

1. Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

2. Model Studies of Topaquinone-Dependent Amine Oxidases. 2. Characterization of Reaction Intermediates and Mechanism

3. Cytochrome P-450, Structure, Mechanism, and Biochemistry , ed. P. R. Ortiz de Montellano , Kluwer Academic Plenum , New York , 3rd edn, 2005

4. Mechanistic Study of the Oxidative N-Dealkylation Reactions of Bis(μ-oxo)dicopper Complexes

5. Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry

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