Surface effects on a photochromic spin-crossover iron(ii) molecular switch adsorbed on highly oriented pyrolytic graphite

Author:

Poggini Lorenzo1234ORCID,Londi Giacomo1234ORCID,Milek Magdalena5678,Naim Ahmad910111213ORCID,Lanzilotto Valeria1234ORCID,Cortigiani Brunetto1234,Bondino Federica1415164ORCID,Magnano Elena1415164,Otero Edwige171819,Sainctavit Philippe171819209,Arrio Marie-Anne209212219,Juhin Amélie209212219,Marchivie Mathieu910111213,Khusniyarov Marat M.5678ORCID,Totti Federico1234ORCID,Rosa Patrick910111213ORCID,Mannini Matteo1234ORCID

Affiliation:

1. Department of Chemistry “Ugo Schiff” and INSTM Research Unit of Firenze

2. University of Firenze

3. I-50019 Sesto Fiorentino

4. Italy

5. Department of Chemistry and Pharmacy

6. Friedrich-Alexander University Erlangen-Nürnberg (FAU)

7. Erlangen

8. Germany

9. CNRS

10. Univ. Bordeaux

11. ICMCB

12. UMR5026

13. F-33600 Pessac

14. CNR-IOM

15. Laboratorio TASC

16. 34149 Trieste

17. Synchrotron SOLEIL L'Orme des Merisiers Saint Aubin

18. Gif sur Yvette

19. France

20. IMPMC-UMR7590

21. Sorbonne université

22. 75005 Paris

Abstract

Thin films of Fe(ii) complex with a diarylethene-based ligand featuring spin-crossover have been grown by sublimation in ultra-high vacuum on highly oriented pyrolytic graphite and spectroscopically characterized through a multi technique approach.

Funder

Deutsche Forschungsgemeinschaft

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université de Bordeaux

Seventh Framework Programme

H2020 European Research Council

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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