Substrate-dependent spin crossover in an Fe(ii) scorpionate complex

Author:

Pénicaud Margaux1ORCID,Martinez Edoardo2,Serrano Giulia23ORCID,Cortigiani Brunetto2,Squillantini Lorenzo2,González-Estefan Juan H.1,Velez-Fort Emilio4ORCID,Duttine Mathieu1ORCID,Gonidec Mathieu1ORCID,Rosa Patrick1ORCID,Mannini Matteo2ORCID,Poggini Lorenzo25ORCID

Affiliation:

1. Univ. Bordeaux, CNRS, Bordeaux-INP, ICMCB, UMR 5026, F-33600 Pessac, Cedex, France

2. Department of Chemistry “U. Schiff” (DICUS) and INSTM Research Unit, University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, FI, Italy

3. Department of Industrial Engineering (DIEF) and INSTM Research Unit, University of Florence, Via di Santa Marta, 3, 50139, Florence, Italy

4. European Synchrotron Radiation Facility, 71, avenue des Martyrs CS 40220, 38043 Grenoble, Cedex 9, France

5. Institute for Chemistry of OrganoMetallic Compounds (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy

Abstract

A new spin-crossover complex based on a heteroscorpionate ligand was synthesized and characterized.

Funder

European Cooperation in Science and Technology

Agence Nationale de la Recherche

Ministero dell'Università e della Ricerca

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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