Metastable Ta2N3 with highly tunable electrical conductivity via oxygen incorporation

Author:

Jiang Chang-Ming1234ORCID,Wagner Laura I.1234,Horton Matthew K.56789ORCID,Eichhorn Johanna1234ORCID,Rieth Tim1234,Kunzelmann Viktoria F.1234ORCID,Kraut Max1234ORCID,Li Yanbo10111213ORCID,Persson Kristin A.56789ORCID,Sharp Ian D.1234ORCID

Affiliation:

1. Walter Schottky Institute and Physics Department

2. Technische Universität München

3. 85748 Garching

4. Germany

5. Energy Technologies Area

6. Lawrence Berkeley National Laboratory

7. Berkeley

8. USA

9. Department of Materials Science and Engineering

10. Institute of Fundamental and Frontier Sciences

11. University of Electronic Science and Technology of China

12. Chengdu 610054

13. P. R. China

Abstract

Metastable Ta2N3 with bixbyite structure is directly deposited by reactive magnetron sputtering. Concerted experimental and computational efforts reveal the crucial role of oxygen impurity in both the synthesis and in tuning the electronic structure.

Funder

Basic Energy Sciences

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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