Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C

Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C–H oxidation

Published:2021 Issue:1 Volume:11 Page:537-542
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Frateloreto Federico¹²³⁴⁵^ORCID,Capocasa Giorgio¹²³⁴⁵^ORCID,Olivo Giorgio¹²³⁴⁵,Abdel Hady Karim¹²³⁴⁵,Sappino Carla¹²³⁴⁵^ORCID,Di Berto Mancini Marika¹²³⁴⁵,Levi Mortera Stefano⁶⁷⁸⁵,Lanzalunga Osvaldo¹²³⁴⁵^ORCID,Di Stefano Stefano¹²³⁴⁵^ORCID

Affiliation:

1. Dipartimento di Chimica and Istituto CNR per i Sistemi Biologici (ISB-CNR)

2. Sezione Meccanismi di Reazione

3. Università di Roma La Sapienza

4. 00185 Rome

5. Italy

6. Area of Genetics and Rare Diseases

7. Unit of Human Microbiome

8. Bambino Gesù Children's

Abstract

A case in which the insertion of large and hindering groups in the catalyst backbone does not cause the insurgence of steric effects on the catalysed reaction.

Funder

Università di Roma La Sapienza

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D0RA09677F

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4. Site-selective and stereoselective functionalization of unactivated C–H bonds

5. Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage CH Azidation

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