N-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction-Reference-Cited by-同舟云学术

N-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction

Published:2017 Issue:36 Volume:46 Page:12053-12066
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Waters Jordan B.¹²³⁴⁵^ORCID,Chen Qien¹²³⁴⁵,Everitt Thomas A.¹²³⁴⁵,Goicoechea Jose M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Oxford

3. Chemistry Research Laboratory

4. Oxford

5. UK

Abstract

The reactivity of the heavier group 15 tribromides, SbBr₃ and BiBr₃, towards 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) is described.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02431B

Reference49 articles.

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2. G. Bertrand , Carbene Chemistry: From Fleeting Intermediates to Powerful Reagents, Marcel Dekker, New York, 2002

3. N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis

4. F. Glorius , N-Heterocyclic Carbenes in Transition Metal Catalysis (Topics in Organometallic Chemistry 21), Springer-Verlag, Berlin-Heidelberg, Germany, 2006

5. S. P. Nolan , N-Heterocyclic Carbenes in Synthesis, Wiley-VCH, Weinheim, Germany, 2006

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