Revisiting a (001)-oriented layered lead chloride templated by 1,2,4-triazolium: structural phase transitions, lattice dynamics and broadband photoluminescence

Author:

Mączka Mirosław1ORCID,Sobczak Szymon2ORCID,Ptak Maciej1ORCID,Smółka Szymon1,Fedoruk Katarzyna3,Dybała Filip4,Herman Artur P.4ORCID,Paraguassu Waldeci5,Zaręba Jan K.6ORCID,Kudrawiec Robert4,Sieradzki Adam3ORCID,Katrusiak Andrzej2ORCID

Affiliation:

1. W. Trzebiatowski Institute of Low Temperature and Structural Research of the Polish Academy of Sciences, Okólna 2, 50-422 Wroclaw, Poland

2. Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland

3. Department of Experimental Physics, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

4. Department of Semiconductor Materials Engineering, Faculty of Fundamental Problems of Technology, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

5. Faculdade de Fisica, Universidade Federal do Para, 66075-110 Belem, Brazil

6. Advanced Materials Engineering and Modeling Group, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370, Wrocław, Poland

Abstract

Layered 1,2,4-triazolium lead chloride undergoes three phase transitions. It also exhibits narrow and broad emissions, which exhibit different temperature dependence. We correlated this behaviour with the change of the octahedral distortion.

Funder

Politechnika Wrocławska

Publisher

Royal Society of Chemistry (RSC)

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