Intramolecular attack on coordinated nitriles: metallacycle intermediates in catalytic hydration and beyond-Reference-Cited by-同舟云学术

Intramolecular attack on coordinated nitriles: metallacycle intermediates in catalytic hydration and beyond

Published:2021 Issue:44 Volume:50 Page:15953-15960
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Glueck David S.¹^ORCID

Affiliation:

1. 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, New Hampshire, 03755, USA

Abstract

Intramolecular S-OH or P-OH attack on a coordinated nitrile yields a metallacycle in the proposed mechanism of nitrile hydratase and related synthetic catalysts.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02795F

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