Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes

Author:

Huang Wei1,Lu Jiahui2,Fan Qingqing1,Li Xiaoyan1ORCID,Hinz Alexander3ORCID,Sun Hongjian1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Shanda Nanlu 27, 250100 Jinan, People's Republic of China

2. School of Chemsitry and Chemical Engineering, University of Jinan, 250022 Jinan, People's Republic of China

3. Karlsruhe Institute of Technology (KIT), Institute of Inorganic Chemistry, Engesserstr.15, 76131 Karlsruhe, Germany

Abstract

Four aryl Co and Fe complexes, (F4C5N)CoCl(PMe3)3 (1), (F4C5N)Fe(PMe3)4 (2), (F5C6)CoCl(PMe3)3 (3) and (F4C5)FeCl(PMe3)3 (4), were synthesized from the reactions of 3-chloro-2,4,5,6-tetrafluoro-pyridine and chloropentafluorobenzene with Co(PMe3)4 and Fe(PMe3)4, respectively.

Funder

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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