Towards deliberate design of persistent phosphors: a study of La–Ga admixing in LuAG:Ce crystals to engineer elemental homogeneity and carrier trap depths

Author:

Bartosiewicz Karol1ORCID,Fritz Verena2ORCID,Van der Heggen David2ORCID,Szymanski Damian3ORCID,Zeler Justyna4ORCID,Pejchal Jan5ORCID,Yamaji Akihiro6,Kucerkova Romana5,Beitlerova Alena5,Kurosawa Shunsuke6789,Yoshikawa Akira67,Smet Philippe F.2ORCID,Zych Eugeniusz4ORCID,Nikl Martin5ORCID

Affiliation:

1. Faculty of Physics, Kazimierz Wielki University in Bydgoszcz, Powstancow Wielkopolskich 2, 85-090, Bydgoszcz, Poland

2. LumiLab, Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, Ghent, 9000, Belgium

3. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna 2, Wrocław, 50-422, Poland

4. University of Wrocław, Faculty of Chemistry, 14 F. Joliot-Curie Street, Wrocław 50-383, Poland

5. Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 1999/2, 182 00 Praha, Czech Republic

6. Institute for Materials Research, Tohoku University, 2-1-1 Katahira Aoba-ku, Sendai, Miyagi 980-8577, Japan

7. New Industry Creation Hatchery Center, Tohoku University, 2-1-1 Katahira Aoba-ku, Sendai, Miyagi 980-8577, Japan

8. Institute of Laser Engineering, Osaka University, 2-6 Yamadaoka, Suita, Osaka 565-0871, Japan

9. Faculty of Science, Yamagata University, 1-4-12, Kojirakawa-machi, Yamagata 990-8560, Japan

Abstract

Persistent luminescence in Lu3Al2Ga2O12:Ce,La crystal was studied. La codoping elongated luminescence and increased trapping centers. The influence of La on crystal growth, structure, and Al/Ga sublattices was analyzed.

Funder

Grantová Agentura České Republiky

Fonds Wetenschappelijk Onderzoek

Narodowe Centrum Nauki

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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