The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control
Author:
Affiliation:
1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Abstract
Funder
École Polytechnique Fédérale de Lausanne
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT04039E
Reference38 articles.
1. Synthesis of homoleptic tris(organo-chelate)iridium(III) complexes by spontaneous ortho-metallation of electronrich olefin-derived N,N′-diarylcarbene ligands and the X-ray structures of fac-[6H3Me-p}3] and mer-6H3Me-p}2 {C6H4Me-p}Cl (a product of HCl cleavage)
2. Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands
3. Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical Properties
4. Cyclometalated Ir(iii) complexes towards blue-emissive dopant for organic light-emitting diodes: fundamentals of photophysics and designing strategies
5. Phosphorescent Tris ‐Bidentate Ir III Complexes with N‐Heterocyclic Carbene Scaffolds: Structural Diversity and Optical Properties
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1. Iridium(III) Carbene Phosphors with Fast Radiative Transitions for Blue Organic Light Emitting Diodes and Hyperphosphorescence;Advanced Functional Materials;2024-01-03
2. Blue Electrophosphorescence from Iridium(III) Phosphors Bearing Asymmetric Di‐N‐aryl 6‐(trifluoromethyl)‐2H‐imidazo[4,5‐b]pyridin‐2‐ylidene Chelates;Advanced Materials;2023-09-21
3. Peripheral engineering of Ir(iii) emitters with imidazo[4,5-b]pyrazin-2-ylidene cyclometalates for blue organic light emitting diodes;Journal of Materials Chemistry C;2023
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