Peripheral engineering of Ir(iii) emitters with imidazo[4,5-b]pyrazin-2-ylidene cyclometalates for blue organic light emitting diodes

Author:

Yan Jie1ORCID,Wu Yixin1,Peng I-Che2,Pan Yi1ORCID,Yiu Shek-Man1,Wong Ken-Tsung3ORCID,Hung Wen-Yi2ORCID,Chi Yun1ORCID,Lau Kai-Chung1ORCID

Affiliation:

1. Department of Materials Sciences and Engineering, Department of Chemistry, and Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong

2. Department of Optoelectronics and Materials Technology, National Taiwan Ocean University, Keelung 20224, Taiwan

3. Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan

Abstract

A new class of Ir(iii) carbene complexes with dual N-aryl appendages, the isomeric products of which were successfully isolated and purified by column chromatography, were synthesized followed by catalytic isomerization at elevated temperature.

Funder

Research Grants Council, University Grants Committee

National Science and Technology Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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