Latent harmony in dicarbon between VB and MO theories through orthogonal hybridization of 3σg and 2σu
Author:
Affiliation:
1. Institute of Functional Material Chemistry & Local United Engineering Lab for Power Battery
2. Faculty of Chemistry
3. Northeast Normal University
4. Changchun 130024
5. China
Abstract
Besides the classic double bond scheme, several novel schemes have been proposed to describe the nature of the chemical bond in dicarbon, including a quadruple bond and a singlet diradical state. The results presented here show a harmony between MO and VB theories.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jilin Province
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03437J
Reference33 articles.
1. Note on Electronic States of Diatomic Carbon, and the Carbon-Carbon Bond
2. Carbon molecules, ions, and clusters
3. C2 spectroscopy and kinetics
4. Chemistry of the singlet and triplet C2 molecules. Mechanism of acetylene formation from reaction with acetone and acetaldehyde
Cited by 25 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Mimicking the C2 molecule: M2B2 and M3B2+ clusters (M = Li, Na) and the reactivity of the N-heterocyclic carbene bound Li2B2 complex;Physical Chemistry Chemical Physics;2023
2. Eliminating all bonds from the ground state gives rise to ionic bonding in high-spin states of heterodiatomics;Physical Chemistry Chemical Physics;2023
3. On the nature of the chemical bond in valence bond theory;The Journal of Chemical Physics;2022-09-07
4. A Critical Look at Linus Pauling’s Influence on the Understanding of Chemical Bonding;Molecules;2021-08-03
5. The nature of the chemical bond in the dicarbon molecule;The Journal of Chemical Physics;2020-10-28
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3