A new reductant in gold cluster chemistry gives a superatomic gold gallium cluster

Author:

Fetzer Florian12345,Schrenk Claudio12345ORCID,Pollard Nia678910ORCID,Adeagbo Adebola678910ORCID,Clayborne Andre Z.678910ORCID,Schnepf Andreas12345ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Universität Tübingen

3. Auf der Morgenstelle 18

4. Tübingen D-72076

5. Germany

6. Department of Chemistry

7. Howard University

8. 525 College Street NW

9. Washington

10. USA

Abstract

The intermetalloid cluster [Au9GaCl2(PPh3)8]2+ is obtained by using GaCp as a reducing agent in gold chemistry for the first time, being a rare exception in the borane-dominated field of reductants used for gold chemistry.

Funder

National Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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