Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system-Reference-Cited by-同舟云学术

Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system

Published:2017 Issue:8 Volume:46 Page:2439-2444
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lazreg Faïma¹²³⁴,Guidone Stefano¹²³⁴,Gómez-Herrera Alberto¹²³⁴,Nahra Fady⁵⁶⁷⁸,Cazin Catherine S. J.¹²³⁴⁵^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. University of St Andrews

3. St Andrews

4. UK

5. Department of Inorganic and Physical Chemistry

6. Ghent University

7. 9000 Gent

8. Belgium

Abstract

A dual catalytic process based on a heterobimetallic system, consisting of Cu-NHC and Au-NHC complexes, was shown to be highly active and selective for the hydrophenoxylation of internal alkynes.

Funder

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04513H

Reference64 articles.

1. Modern Acetylene Chemistry, ed. P. J. Stang and F. Diederich, VCH, Weinhein, 1995

2. Acetylene Chemistry, ed. F. Diederich, P. J. Stang and R. R. Tykwinski, Wiley-VCH, Weinheim, 2005

3. Transition metal-catalyzed addition of C-, N- and O-nucleophiles to unactivated C–C multiple bonds

4. Chemicals from Alkynes with Palladium Catalysts

5. Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes

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