Mechanistic Study of Alkyne Insertion into Cu–Al and Au–Al Bonds: A Paradigm Shift for Coinage Metal Chemistry
Author:
Affiliation:
1. Department of Chemistry, Biology and Biotechnologies, University of Perugia, Via Elce di Sotto, 8-06123 Perugia, Italy
2. CNR Institute of Chemical Science and Technologies ″Giulio Natta″ (CNR-SCITEC), Via Elce di Sotto, 8-06123 Perugia, Italy
Funder
Ministero dell?Istruzione, dell?Universit? e della Ricerca
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.2c03713
Reference62 articles.
1. A nucleophilic gold complex
2. Coinage metal aluminyl complexes: probing regiochemistry and mechanism in the insertion and reduction of carbon dioxide
3. Ambiphilic Al−Cu Bonding
4. On the reactivity of Al-group 11 (Cu, Ag, Au) bonds
5. Reactivity of a Gold-Aluminyl Complex with Carbon Dioxide: A Nucleophilic Gold?
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