Re-examining the Chevrel phase Mo6S8 cathode for Mg intercalation from an electronic structure perspective
Author:
Affiliation:
1. Materials Theory
2. ETH Zürich
3. 8093 Zürich
4. Switzerland
5. Joint Center for Energy Storage Research (JCESR)
6. The Molecular Foundry
7. Lawrence Berkeley National Laboratory
8. Berkeley
9. 94720, USA
Abstract
The metallic cathode material Mo6S8 allows for highly localized electronic screening that shields the Mg2+ charge and ease its diffusion.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03046C
Reference22 articles.
1. Prototype systems for rechargeable magnesium batteries
2. Application of first-principles calculations to the design of rechargeable Li-batteries
3. A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries
4. On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials
5. The effect of the anionic framework of MoX Chevrel Phase (X=S, Se) on the thermodynamics and the kinetics of the electrochemical insertion of Mg ions
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