Site-specific hydrogen-atom elimination in photoexcited alkyl radicals-Reference-Cited by-同舟云学术

Site-specific hydrogen-atom elimination in photoexcited alkyl radicals

Published:2021 Issue:3 Volume:23 Page:2458-2468
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chicharro David V.¹²³^ORCID,Zanchet Alexandre⁴⁵³^ORCID,Bouallagui Aymen⁴⁵³⁶⁷,Rubio-Lago Luis¹²³,García-Vela Alberto⁴⁵³^ORCID,Bañares Luis¹²³⁸⁹,Marggi Poullain Sonia¹²³¹⁰¹¹^ORCID

Affiliation:

1. Departamento de Química Física (Unidad Asociada I + D + i al CSIC), Facultad de Ciencias Químicas, Universidad Complutense de Madrid

2. 28040 Madrid

3. Spain

4. Instituto de Física Fundamental, Consejo Superior de Investigaciones Científicas

5. 28006 Madrid

6. Laboratoire de Spectroscopie Atomique, Moléculaire et Applications-LSAMA LR01ES09, Faculté des Sciences de Tunis, Université de Tunis El Manar

7. Tunis

8. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanoscience), Cantoblanco

9. 28049 Madrid

10. Department of Chemistry, University of California, Berkeley

11. USA

Abstract

A prompt site-specific hydrogen-atom elimination from the α-carbon atom is reported in the photodissociation of several alkyl radicals at 201 nm and discussed in terms of their chemical structure and the role of vibrational promoting modes.

Funder

H2020 Marie Skłodowska-Curie Actions

Ministerio de Ciencia e Innovación

Consejo Superior de Investigaciones Científicas

Secretaría de Estado de Investigación, Desarrollo e Innovación

Universidad Complutense de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05410K