Poly(4-vinylpyridine)-nitrating mixture complex (PVP-NM): solid nitrating mixture equivalent for safe and efficient aromatic nitration

Author:

Surya Prakash G. K.1234,Gurung Laxman1234,Glinton Kevin E.1234,Belligund Kavita1234,Mathew Thomas1234,Olah George A.1234

Affiliation:

1. Loker Hydrocarbon Research Institute and Department of Chemistry

2. University of Southern California

3. Los Angeles

4. USA

Abstract

PVP-NM prepared from poly(4-vinylpyridine) and nitrating mixture (1 : 1 mixture of HNO3 and H2SO4) is a safe and effective nitrating agent for both activated and deactivated arenes under mild conditions. The polymer can be retrieved and reused without losing the efficacy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference46 articles.

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3. Ueber die Zusammensetzung des Nitrobenzids und Sulfobenzids;

4. K. Schofield , Aromatic Nitration, Cambridge University Press, Cambridge, 1980

5. J. G. Hoggett , R. B.Moodie, J. R.Penton and K.Schofield, Nitration and Aromatic Reactivity, Cambridge University Press, Cambridge, 1971

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