Structural dimension modulation in a new oxysulfide system of Ae2Sb2O2S3 (Ae = Ca and Ba)-Reference-Cited by-同舟云学术

Structural dimension modulation in a new oxysulfide system of Ae₂Sb₂O₂S₃ (Ae = Ca and Ba)

Published:2022 Issue:14 Volume:9 Page:3552-3558
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Wang Ruiqi¹,Zhao Yantao¹,Zhang Xian²^ORCID,Huang Fuqiang¹³^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

2. Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology, Beijing, 100094 P. R. China

3. State Key Laboratory of High-Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Abstract

Two oxysulfides Ae2Sb2O2S3 (Ae = Ca, Ba) with different structural dimensions were successfully discovered. Ca2Sb2O2S3 contains one-dimensional [Sb2O2S3]4− chains, while Ba2Sb2O2S3 features zero-dimensional [Sb2O2S3]4− clusters.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00698G

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1. Pressure-induced superconductivity in the layered pnictogen diselenide NdO0.8F0.2Sb1−xBixSe2(x=0.3and0.7)

2. Superconductivity in Novel BiS2-Based Layered Superconductor LaO1-xFxBiS2