Self-assembly of [PNbxW12−xO40]n− Keggin anions – a simple way to mixed Nb–W polyoxometalates

Author:

Abramov Pavel A.12342,Shmakova Alexandra A.12342,Haouas Mohamed56789,Fink Gerhard56789,Cadot Emmanuel56789,Sokolov Maxim N.12342

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. Novosibirsk

3. Russia

4. Novosibirsk State University

5. Lavoisier Institute of Versailles

6. UMR CNRS 8180

7. University of Versailles Saint-Quentin en Yvelines

8. 78035 Versailles

9. France

Abstract

This paper summarizes preparations of mixed phosphoniobotungstates [PNbxW12−xO40](3+x)− (x = 1–3) based on two different ways: incorporation of Nb into pre-existing lacunary-type phosphotungstates and self-assembly reactions.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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