Triniobium Polytungstophosphates. Syntheses, Structures, Clarification of Isomerism and Reactivity in the Presence of H2O2
Author:
Affiliation:
1. Department of Chemistry, Emory University, Atlanta, Georgia 30322
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic980467z
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2. Trisubstituted heteropolytungstates as soluble metal oxide analogues. 4. The synthesis and characterization of organic solvent-soluble (Bu4N)12H4P4W30Nb6O123 and (Bu4N)9P2W15Nb3O62 and solution spectroscopic and other evidence for the supported organometallic derivatives (Bu4N)7[(C5Me5)Rh.cntdot.P2W15Nb3O62] and (Bu4N)7[(C6H6)Ru.cntdot.P2W15Nb3O62]
3. A novel triperoxyniobium-containing polyoxoanion, SiW9(NbO2)3O377−: synthesis, characterization, catalytic allylic epoxidations with H2O2 and preliminary kinetic studies
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