Trinuclear (aminonitrone)ZnII complexes as key intermediates in zinc(ii)-mediated generation of 1,2,4-oxadiazoles from amidoximes and nitriles
Author:
Affiliation:
1. Institute of Chemistry
2. Saint Petersburg State University
3. Saint Petersburg
4. Russian Federation
5. Center for X-ray Diffraction Studies
Abstract
Amidoximes react with zinc salts in undried EtOAc furnishing the trinuclear species, where amidoximes are stabilized in the aminonitrone form.
Funder
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03508F
Reference92 articles.
1. Zinc(II)-Mediated Nitrile–Amidoxime Coupling Gives New Insights into H+-Assisted Generation of 1,2,4-Oxadiazoles
2. PTSA−ZnCl2: An Efficient Catalyst for the Synthesis of 1,2,4-Oxadiazoles from Amidoximes and Organic Nitriles
3. New synthesis of 1,2,4-oxadiazoles
4. 15N NMR study of the mechanism of the reaction of amidoximes with nitrites in the presence of ZnCl2 and HCl
5. Reaction of organic nitriles with benzamidoxime
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