Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination-Reference-Cited by-同舟云学术

Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination

Published:2018 Issue:18 Volume:9 Page:4235-4243
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dhara Debabrata¹²³^ORCID,Kalita Pankaj⁴⁵⁶³^ORCID,Mondal Subhadip¹²³,Narayanan Ramakirushnan Suriya¹²³^ORCID,Mote Kaustubh R.¹²³^ORCID,Huch Volker⁷⁸⁹¹⁰,Zimmer Michael⁷⁸⁹¹⁰,Yildiz Cem B.¹¹¹²¹³¹⁴^ORCID,Scheschkewitz David⁷⁸⁹¹⁰^ORCID,Chandrasekhar Vadapalli¹²³¹⁵¹⁶^ORCID,Jana Anukul¹²³^ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad

2. Hyderabad-500107

3. India

4. School of Chemical Sciences

5. National Institute of Science Education and Research

6. Bhubaneswar-752050

7. Krupp-Chair of General and Inorganic Chemistry

8. Saarland University

9. 66123 Saarbrücken

10. Germany

11. Department of Medicinal and Aromatic Plants

12. University of Aksaray

13. Aksaray

14. Turkey

15. Department of Chemistry

16. Indian Institute of Technology Kanpur

Abstract

The reversible coordination of an N-heterocyclic carbene (NHC) enhances the reactivity of a diphosphene towards hydrolysis and transfer hydrogenation. The hydrolysis is catalytic in NHC.

Funder

Tata Institute of Fundamental Research

Saarland University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00348C

Reference45 articles.

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2. Nature of chlorotris(triphenylphosphine)rhodium in solution and its reaction with hydrogen