Abrupt two-step and symmetry breaking spin crossover in an iron(iii) complex: an exceptionally wide [LS

Abrupt two-step and symmetry breaking spin crossover in an iron(iii) complex: an exceptionally wide [LS–HS] plateau

Author:

Harding David J.¹²³⁴⁵,Phonsri Wasinee¹²³⁴⁵,Harding Phimphaka¹²³⁴⁵,Murray Keith S.⁶⁷⁸⁹,Moubaraki Boujemaa⁶⁷⁸⁹,Jameson Guy N. L.¹⁰¹¹¹²¹³

Affiliation:

1. Molecular Technology Research Unit

2. School of Science

3. Walailak University

4. Thasala

5. Thailand

6. School of Chemistry

7. Monash University

8. Clayton

9. Australia

10. Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology

11. University of Otago

12. Dunedin

13. New Zealand

Abstract

A rare iron(iii) symmetry breaking spin crossover compound with an extremely wide [LS–HS] plateau is reported.

Funder

Thailand Research Fund

National Science and Technology Development Agency

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

Reference32 articles.

1. Spin-Crossover Materials: Properties and Applications, ed. M. A. Halcrow, John Wiley & Sons Ltd, Chichester, 2013

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