Synthesis, mixed-spin-state structure and Langmuir–Blodgett deposition of amphiphilic Fe(iii) quinolylsalicylaldiminate complexes

Author:

Poungsripong Peeranuch1ORCID,Boonprab Theerapoom2ORCID,Harding Phimphaka2ORCID,Murray Keith S.3ORCID,Phonsri Wasinee3ORCID,Zhang Ningjin4,Kitchen Jonathan A.56ORCID,Harding David J.2ORCID

Affiliation:

1. Functional Materials and Nanotechnology Center of Excellence, Walailak University, Thasala, Nakhon Si Thammarat, 80160, Thailand

2. School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand

3. School of Chemistry, Monash University, Clayton, VIC, 3800, Australia

4. School of Chemistry, University of Southampton, University Road, Southampton, SO17 1BJ, UK

5. Department of Chemistry, Auckland University of Technology, New Zealand

6. The MacDiarmid Institute for Advanced Materials and Nanotechnology, New Zealand

Abstract

Three amphiphilic iron(iii) spin crossover complexes are reported which form stable Langmuir–Blodgett films. The alkyl chains also modulate spin crossover behaviour.

Publisher

Royal Society of Chemistry (RSC)

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