New method for in situ generation of enolate-iminium 1,4-dipoles for [4 + 2] and [4 + 1] dipolar heterocycloaddition reactions

Author:

Zhulanov Vladimir E.1234,Dmitriev Maksim V.1234,Maslivets Andrey N.1234,Rubin Michael15641

Affiliation:

1. Department of Chemistry

2. Perm State University

3. Perm 614990

4. Russian Federation

5. North Caucasus Federal University

6. Stavropol 355009

Abstract

Thermolysis of N-(diphenylenamino)pyrrolediones proceeds with formation of dihydropyrazolone 1,4-dipoles. [4 + 4] Homodimerizations and a series of [4 + 2] and [4 + 1] cycloadditions of these species with various dipolarophiles were investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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