Clathrochelates meet phosphorus. New thio- and phosphorylation reactions of an iron(ii) dichloroclathrochelate precursor and preparation of its first phosphorus(iii)-containing macrobicyclic derivative
Author:
Affiliation:
1. Nesmeyanov Institute of the Organoelement Compounds of the Russian Academy of Sciences
2. Moscow
3. Russia
4. Gubkin Russian State University of Oil and Gas
Abstract
(Thio)phosphorylation of an iron(ii) dichloroclathrochelate gave PV,Cl- and PV,PV-substituted cage complexes, undergoing chemical reduction to their phosphorus(iii)-containing derivatives.
Funder
Russian Foundation for Basic Research
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00164E
Reference10 articles.
1. Clathrochelates meet phosphorus: thiophosphorylation of Fe(ii) dichloroclathrochelate precursor, synthesis of N,S-donor macrobicyclic ligands and their Pd(ii) complexes as potent catalysts of Suzuki cross-coupling reaction
2. Phase Transfer Catalysis in Phosphorus Chemistry
3. Clathrochelate monoribbed-functionalized iron(ii) α-dioximates: synthetic pathways and structural and electrochemical features
4. First “Click” Synthesis of the Ribbed‐Functionalized Metal Clathrochelates: Cycloaddition of Benzyl Azide to Propargylamine Iron(II) Macrobicycle and the Unexpected Transformations of the Resulting Cage Complex
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