Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes-Reference-Cited by-同舟云学术

Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

Published:2021 Issue:84 Volume:57 Page:11060-11063
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Shylin Sergii I.¹²^ORCID,Pogrebetsky James L.¹,Husak Alina O.¹³,Bykov Dmytro⁴,Mokhir Andriy⁵^ORCID,Hampel Frank⁵,Shova Sergiu⁶,Ozarowski Andrew⁷^ORCID,Gumienna-Kontecka Elzbieta⁸,Fritsky Igor O.¹³^ORCID

Affiliation:

1. Department of Chemistry, Taras Shevchenko National University of Kyiv, 64, Volodymyrska Str., 01601 Kiev, Ukraine

2. Department of Chemistry – Ångström Laboratory, Uppsala University, PO Box 523, 75120 Uppsala, Sweden

3. PBMR Labs Ukraine, Murmanska 1, 02094 Kiev, Ukraine

4. National Center for Computational Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

5. Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, Nikolaus-Fiebiger-Str. 10, 91058 Erlangen, Germany

6. “Poni Petru” Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41A, 700487 Iasi, Romania

7. National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA

8. Faculty of Chemistry, University of Wrocław, F. Joliot-Curie Str. 14, 50-383 Wrocław, Poland

Abstract

Mn(iv) cation encapsulated in the hexahydrazide cage is indefinitely stable in solid state, organic solvents and aqueous solutions.

Funder

Ministry of Education and Science of Ukraine

Horizon 2020 Framework Programme

National High Magnetic Field Laboratory

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04870H

Reference30 articles.

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2. Y.Voloshin , I.Belaya and R.Krämer , Cage metal complexes: Clathrochelates revisited , Springer , 2017

3. Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

4. Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

5. Photoinduced hole transfer from tris(bipyridine)ruthenium dye to a high-valent iron-based water oxidation catalyst

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