Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method-Reference-Cited by-同舟云学术

Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

Published:2022 Issue:57 Volume:58 Page:7992-7995
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Breton Logan S.¹,Morrison Gregory¹,Lacroix Matthew R.²,Halasyamani P. Shiv²,zur Loye Hans-Conrad¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, USA

2. Department of Chemistry, University of Houston, Houston, TX, USA

Abstract

Single crystals of LnBS3 (Ln = La–Nd) were synthesized by the combined boron–chalcogen mixture and molten flux growth methods. SHG measurements confirmed the expectation that LaBS3 would exhibit a strong SHG response, measured at 1.5 × KDP.

Funder

Basic Energy Sciences

National Science Foundation

Welch Foundation

Division of Materials Sciences and Engineering

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01260J

Reference29 articles.

1. Ba4(BS3S)2S4: a new thioborate with unprecedented [BS3-S] and [S4] fundamental building blocks

2. Thioborates: potential nonlinear optical materials with rich structural chemistry

3. Ba2BS3Cl and Ba5B2S8Cl2: First alkaline-earth metal thioborate halides with [BS3] units

4. Recent advances in rare earth-based borate single crystals: Potential materials for nonlinear optical and laser applications

5. Synthesis of the Thioborate Crystal ZnxBa2B2S5+x (x ≈ 0.2) for Second Order Nonlinear Optical Applications

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