Cationic rhenium(iii) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes
Author:
Affiliation:
1. Department of Chemistry
2. North Carolina State University
3. Raleigh
4. USA
Abstract
Cationic Re(iii) complexes are shown to be more active for the catalytic hydrosilylation of benzaldehydes than their neutral acetate precursors.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00271H
Reference32 articles.
1. B. Marciniec , Comprehensive Handbook on Hydrosilylation, Elsevier, 2013
2. Scope and Mechanistic Studies of Catalytic Hydrosilylation with a High-Valent Nitridoruthenium(VI)
3. An Efficient Catalyst Based on Manganese Salen for Hydrosilylation of Carbonyl Compounds
4. Computational Study on the Reaction Mechanism of Hydrosilylation of Carbonyls Catalyzed by High-Valent Rhenium(V)−Di-oxo Complexes
5. Catalyzing Aldehyde Hydrosilylation with a Molybdenum(VI) Complex: A Density Functional Theory Study
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