Re–Silane complexes as frustrated lewis pairs for catalytic hydrosilylation
Author:
Affiliation:
1. Department of Chemistry
2. North Carolina State University
3. Raleigh
4. USA
Abstract
A pathway for the catalytic hydrosilylation of carbonyl substrates was calculated by DFT(B3PW91-D3) for both cationic and neutral Re(iii) species. This mechanism is similar to the pathway calculated for M(C6F5)3 (M = B, Al and Ga) catalysts.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02084B
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