Iridium–NSiN catalyzed formation of silylphosphinecarboxylates from the reaction of CO2 with P(SiMe3)R2 (R = Ph, Cy)

Author:

Julián Alejandro12345,Polo Víctor67345ORCID,Fernández-Alvarez Francisco J.12345,Oro Luis A.12345ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

3. Universidad de Zaragoza

4. Zaragoza

5. Spain

6. Departamento de Química Física

7. Instituto de Biocomputación y Física de Sistemas Complejos (BIFI)

Abstract

Iridium-catalyzed insertion of CO2 into the P-SiMe3 bond of P(SiMe3)R2 (R = Ph, Cy) to give P(C(O)OSiMe3)R2 species.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference41 articles.

1. Carbon dioxide as chemical feedstock, ed. M. Aresta, Wiley-VCH, Weinheim, 2010

2. M. Aresta , in Carbon Dioxide Reduction and Uses as a Chemical Feedstock, in Activation of Small Molecules, ed. W. B. Tolman, Wiley-VCH, Weinheim, 2006

3. Recent advances in the homogeneous hydrogenation of carbon dioxide

4. Homogeneous catalytic reduction of CO2 with hydrosilanes

5. Using carbon dioxide as a building block in organic synthesis

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