Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe2Ph catalyzed by iridium complexes-Reference-Cited by-同舟云学术

Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe2Ph catalyzed by iridium complexes

Published:2019 Issue:13 Volume:48 Page:4255-4262
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Guzmán Jefferson¹²³⁴,Bernal Ana M.¹²³⁴,García-Orduña Pilar¹²³⁴,Lahoz Fernando J.¹²³⁴^ORCID,Oro Luis A.¹²³⁴^ORCID,Fernández-Alvarez Francisco J.¹²³⁴^ORCID

Affiliation:

1. Departamento de Química Inorgánica – Instituto de Síntesis Química y Catálisis Homogénea (ISQCH). Universidad de Zaragoza – CSIC

2. Facultad de Ciencias 50009

3. Zaragoza

4. Spain

Abstract

Ir–NSi^tBu based catalysts allow the control of the selective reduction of formamides with HSiMe₂Ph to afford O-silylated hemiaminals or methylamines.

Funder

Ministerio de Economía y Competitividad

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05070H

Reference80 articles.

1. Late Transition Metal-Catalyzed Hydroamination and Hydroamidation

2. Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation